Stratigraphy of total metals in PIRLA sediment cores   总被引：1，自引：0，他引：1  

Stephen A. Norton  Ray W. Bienert Jr.  Michael W. Binford  Jeffrey S. Kahl 《Journal of Paleolimnology》1992,7(3):191-214

Sediment cores from 30 low-alkalinity lakes in northern New England (NE), New York (NY), the northern Great Lakes States (NGLS) of Minnesota, Michigan, and Wisconsin, and Florida (FL) have been dated by ²¹⁰Pb and analyzed for water and organic content, eight major elements (Al, Ti, Fe, Mn, Ca, Mg, Na, K) plus four trace metals (Pb, Zn, Cu, and V). Variations in the percentages of major elements through time are dominated by long-term independent variations in the abundance of SiO₂, FeO, and to a lesser extent Ca and Al. Additional variations are caused by varying proportions of inorganic matter. Major variations in chemistry are generally unrelated to documented distrubances in the watersheds; most disturbances are minor fires or selective logging.Accelerated accumulation of Pb from atmospheric sources into sediment first occurs in sediment dated between 1800 and 1850 in NY and NE, slightly later in the NGLS region, and about 1900 in FL. Modern accumulation rates in all areas are comparable (ca. 1 to 4 g cm^–2 yr^–1). Accumulation rates of Pb in some lakes have declined significantly from 1975 to 1985. Atmospheric deposition of anthropogenic Zn and Cu is also indicated by generally increasing accumulation rates in sediment cores, but the record is not as clear nor are chemical profiles in all lakes parallel to the trends in atmospheric emissions inferred on the basis of fossil fuel consumption, smelting, and other industrial activities. Inter-lake variations in profiles of Cu and Zn are large. Vanadium accumulation rates increase by the 1940s in NY and NE, but not until the 1950s in the NGLS region. This timing correlates with regional trends in the combustion of fuel oil, a major source of atmospheric V.Acidification of some of the lakes is suggested by decreases in the concentration and accumulation rates of Mn, Ca, and Zn in recent sediment, relative to other elements of catchment origin. The decreases generally occur slightly before the onset of acidification as indicated by diatoms. Increased sediment accumulation rates for Fe may indicate the acidification of watershed soils. The use of the accumulation rate of TiO₂ as an indicator of rates of erosion and for normalization of trace metal accumulation rates is in question for lakes where the flux of TiO₂ from the atmosphere varies and is a significant fraction of the total flux of TiO₂ to the sediment.This is the thirteenth of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.  相似文献   

柴达木察尔汗盐湖贝壳堤剖面介形类组合及其环境意义   总被引：3，自引：0，他引：3       下载免费PDF全文

张虎才  王强  彭金兰  陈光杰 《第四纪研究》2008,28(1):103-111

柴达木盆地察尔汗贝壳堤剖面记录了约39.7～17.514CkaB.P.期间古湖泊高湖面扩张、收缩的演化历史。剖面中丰富的介形类,皆为我国东部山间盆地～平原区系与西部高原区系常见种。依据青海地区现代介形类分布调查,可知研究剖面高湖面发育期为淡水湖,其中高分异度介形类组合代表近静水的浅湖环境,单种或近单种土星介大量出现层位指示缓流水环境,大量原生双壳类共生可能指示静水、较深水环境。据地层中介形类分布,自下而上划分为7个组合-沉积环境带,分别为:①少量湖沼种出现（积水洼地形成带）——湖泊前期,②单种缓流水种连续出现（湖泊初始形成带）——高湖面初始形成期,③高分异度组合、介形类富集（浅水大湖带）——高湖面水深加大期,④中分异度组合、介形类少量出现（深湖带）——高湖面最盛期,⑤中分异度组合、介形类少量出现、双壳类连续富集（湖泊变浅带）——高湖面略下降期,⑥缓流水介形类繁盛、双壳类多少不等（湖泊水位下降带）——古湖泊退缩期和⑦介形类稀少带——古湖泊快速消亡期。贝壳堤剖面所见双壳类在现代介形类调查区域没有发现,它们在地层中的出现,进一步指示大体相当MIS3阶段时期柴达木盆地比现代更温暖的气候背景,降水条件好于现代。  相似文献   

基于空间信息技术的堰塞湖库容分析方法研究     

陈晓玲  陆建忠  蔡晓斌  李辉  殷守敬 《遥感学报》2008,12(6)

快速准确计算堰塞湖库容,对了解地震堰塞湖险情具有重要的意义.利用遥感和地理信息系统等空间信息技术,提出了一种基于像素的三维水面的计算动库容的方法,能准确计算水面为曲面,包括动库容在内的总库容.该方法利用遥感影像提取水体边界线,与DEM求交后可得到带高程的边界点,利用空间插值技术获得三维水面,然后利用库容计算模型求解.同时,在分析该算法计算效率的基础上,提出了基于河流分段的库容计算优化算法,最后通过实验对比分析了该方法的合理性和优越性.  相似文献   

长江中下游湖泊沉积物铅污染记录——以洪湖、固城湖和太湖为例   总被引：13，自引：8，他引：5       下载免费PDF全文

姚书春  薛滨  朱育新  夏威岚  李世杰 《第四纪研究》2008,28(4):659-666

2002～2005年在长江中下游的洪湖、固城湖和太湖分别采集了沉积物柱样钻孔,测定了总有机碳（TOC）和金属元素包括Pb,Al,Fe,Ti等,并采用²¹⁰Pb和¹³⁷Cs进行了近代沉积物定年。研究结果表明,洪湖钻孔平均沉积速率为0.15cm/a,固城湖平均沉积速率在0.067cm/a,太湖平均沉积速率为0.35～0.41cm/a。根据湖泊沉积物中铅元素与参考元素（Al,Fe和Ti）浓度和TOC的相关关系建立了回归方程,线性关系极显著（p<0.001）。根据回归方程获取了钻孔中铅的背景值变化,研究表明近代沉积物中金属铅不仅仅来源于自然的作用,而人类活动导致铅的累积发生时间都在20世纪70年代,从一个侧面也说明利用沉积物铅含量变化进行断代存在可能性。对太湖钻孔而言,其污染程度要高于洪湖和固城湖。研究结果表明近30年来洪湖和固城湖人为造成湖泊沉积物铅累积量在不断增加,其沉积物铅污染有进一步加重的趋势,应受到科学家和管理部门的关注。  相似文献   

贵州鹅项水库沉积物特征及其土壤侵蚀的意义   总被引：2，自引：0，他引：2       下载免费PDF全文

孙旭波  王红亚 《第四纪研究》2008,28(4):769-778

对位于贵州西南部非喀斯特丘原区的鹅项水库中取得的一沉积物样芯（EX-1）做了¹³⁷Cs,TOC,C/N和粒度分析以及矿物磁性测量。通过对这些分析和测量结果进行解译,推测了在过去的45年（1960～2005年）中这一水库的汇水流域内土壤侵蚀强度的相对变化。在这45年中,鹅项水库流域的土壤侵蚀经历了由弱到强再持续减弱的一个过程。将这一推测结果与流域内降水数据和土地利用/覆被变化资料数据相结合,探究了该流域土壤侵蚀强度变化的原因。与贵州西南部典型喀斯特流域的情况相比,在鹅项流域内,土地利用/覆被变化情况对土壤侵蚀强度的影响相对次要,而降水对土壤侵蚀强度变化的影响则更为重要。这可能主要因为与典型喀斯特流域相比,鹅项流域的土层较厚、植被覆盖较好。  相似文献   

Numerical Modelling of Dissolving and Driving Exploitation of Potash Salt in the Qarhan Playa——A Coupled Model of Reactive olute Transport and Chemical Equilibrium in a Multi-component Underground Brine System     

LI Wenpeng  LIU Zhenying 《《地质学报》英文版》2008,82(5)

Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory. The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented, which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake. And secondly, with a model forming idea oftransport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference, a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory.Meanwhile, the model was applied to model potassium/magnesium transport in Qarhan Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/Magnesium in the mining of salt deposits in Qarhan Salt Lake.  相似文献   

Numerical Modelling of Dissolving and Driving Exploitation of Potash Salt in the Qarhan Piaya——A Coupled Model of Reactive Solute Transport and Chemical Equilibrium in a Multi-component Underground Brine System     

LI Wenpeng 《《地质学报》英文版》2008,(5)

Firstly,the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory.The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented,which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake.And secondly,with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference,a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory. Meanwhile,the model was applied to model potassium/magnesium transport in Qarban Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarban Salt Lake.  相似文献   

太湖流域土壤重金属元素污染历史的重建:以Pb、Cd为例   总被引：5，自引：1，他引：4  

成杭新  赵传冬  庄广民  夏威岚  刘英汉  杨柯  聂海峰 《地学前缘》2008,15(5):167

太湖是位于长江下游的一个大型浅水湖泊,通过对4个代表太湖不同沉积环境的湖底沉积剖面的137Cs和210Pb沉积定年,重建太湖湖底沉积物和太湖来水流域土壤Cd、Pb的污染历史。结果显示:1980年以前,太湖底积物中Cd、Pb含量与流域内的自然背景含量相当,1980年以后,湖底沉积物中的Cd、Pb含量显著增高,这与我国大规模工业化进程的起始时间基本一致,推测工业化进程是湖底沉积物中Cd、Pb含量增加的主要原因。1900年以来太湖湖底沉积物中累积含有Cd和Pb分别为146t和25980t,其中苕溪来水提供的Cd和Pb分别为40t、6777t,宜溧河来水提供的Cd、Pb分别为36t、6023t,其他来水(洮、滆、运河)提供的Cd、Pb分别为71t、13179t,其他来水是太湖Cd、Pd累积的主要输入途径。Cd、Pb累积的高峰期为20世纪80—90年代,1980年以来,运河来水Cd、Pb的输出通量为28.26t、3419t;苕溪流域Cd、Pb的输出总量分别为13.70t、1585t,其中人为源的Cd、Pb为8.90t、610t,人为源输出的Cd、Pb通量占总输出量的64.96%和38.47%;宜溧河流域Cd、Pb的输出总量分别为10.09t、1063t,人为源的Cd、Pb分别6.96t和500t,人为源输出的Cd、Pb通量占总输出量的68.68%和47.08%,表明太湖流域人类活动所导致的Cd已超过自然剥蚀过程,因此削减工业化进程中的Cd、Pb排放总量,控制太湖运河来水的输出通量是改善太湖底积物Cd、Pb环境质量的关键措施。  相似文献   

长江流域沿江镉异常源追踪与定量评估的方法技术研究:以长江流域安徽段为例   总被引：5，自引：1，他引：4  

赵传冬  陈富荣  陈兴仁  赵和苍  夏威岚  聂海峰  孔牧  刘飞  杨柯 《地学前缘》2008,15(5):179

长江全流域性的Cd异常是被中国正在进行的多目标地球化学调查发现的重大生态环境问题。以长江流域安徽段为研究对象,对沿江镉异常源追踪与定量评估的方法技术进行了系统研究。通过对安徽段长江干流及其主要支流悬浮物中元素含量的测量查明:悬浮物是流域内重金属元素大跨度迁移的主要载体;Cd在悬浮物中的富集程度远远大于其他重金属元素,这或许正是Cd可以形成沿江流域性异常的主要原因;长江干流悬浮物中重金属元素含量的变化明显受到沿江支流的影响。安徽段长江干流及其主要支流重金属元素输出通量定量计算结果表明:秋蒲河是安徽段重金属元素输出通量最大的支流,每年在安徽段长江两岸土壤中沉积下约4.45t的Cd。利用悬浮物加密测量、1∶5万土壤测量和岩石测量对顺安河流域Cd异常源追踪结果显示:内生金属矿床特别是铅锌矿是悬浮物中Cd的最大的供应源。采用河漫滩沉积物分层采样技术和同位素测年技术,初步恢复了研究区Cd等重金属元素沉积和污染的地球化学历史,对研究区Cd等重金属元素异常的未来演变趋势进行了预警预测。  相似文献   

重液材料多钨酸钠在青海湖沉积物重力分离中的应用   总被引：1，自引：0，他引：1  

李善营  于炳松  Hailiang DONG  刘英超 《矿物岩石地球化学通报》2008,27(1):69-71

多钨酸钠是一种无毒、易配制、可循环使用、密度高的新型无机重液.本文利用多钨酸钠重液,用离心机重力分离的方法将青海湖沉积物分成低(≤1.9g/cm3)、中(1.2-2.8g/cm3)、高(≥2.8g/cm3)三个密度组分,平均回收率为96.5%.重力分离后的沉积物测试分析发现,有机质主要分布在富粘土矿物的中密度组,揭示了粘土矿物的表面吸附是青海湖底沉积物有机质的主要赋存形式.  相似文献